Parched maize, esp. the Zea everta.

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1854.  The farmer barters with an urchin tradesman for his last pint of pop-corn.Yale Lit. Mag., xx. 29.
  [“Popped corn” occurs on p. 225.]

2

1858.  I got on the cars [after] flattening out an apple-boy and pop-corn vendor.—N.Y. Tribune, Jan. 14. (N.E.D.)

3