In the old potash-making process: Wood ashes after lixiviation and evaporation; impure potassium hydrate. Hence Black-salter, one who makes black salts.
1880. E. Kirke, Garfield, 6/2. Our future President became prime-minister to a black-salter.
1881. W. M. Thayer, Log-Cabin to White Ho., x. Potash in its crude state, was called black-salts. The manufacturer of the article was called a black-salter.